DRJACK wrote:Has anyone here actually donated shares to a charity? What are the mechanics?
Yes, several times, including as we speak. Contact the charity and ask them if they're set up to receive securities. (They need to have a brokerage account.) They'll give you the appropriate account/transfer information.
Then send/fax a written request to your broker with that information. Here's
one example of what you'd need to send. (I found it by Googling on the fax number I use to send my transfer requests to TD Waterhouse.)
Your broker transfers the securities to their broker. AFAIK Canadian discount brokers do the transfers to charitable organizations without charging fees as a gesture of goodwill. (Let's hear a round of applause!) Their broker then sells the securities on the open market.
If you intend to do this, start the ball rolling on Monday. It takes at least a couple of weeks, perhaps more the first time as you learn the details of the process for your charities and broker. Year-end is fast approaching. You can't leave this until New Year's Eve as you can (and I've done) with last-minute cash donations over the Internet

I presume that ABC Charity does not want to physically receive 35 shares of XYZ Corp.
Actually they do and so do you...
Do you simply sell the shares and donate the cash proceeds? If so, what records are required for tax purposes?
No. You have to donate the securities, not the cash proceeds. If you sell first the capital gain is yours and you lose the CG tax exemption.
The charity will send you a receipt that indicates that the contribution was "in-kind". The amount on the receipt is the fair market value. On your tax return you have two steps, (1) claim their amount as a charitable expense and (2) claim the 0% CG inclusion rate on the transferred securities on the schedule for capital gains.
If your charity does not have a broker, there's
Link Charity. (Caveat: I've never used them and only briefly looked at their site in the past.)
Sedulously eschew obfuscatory hyperverbosity and prolixity.